Cyclopentadiene-mediated hydride transfer from rhodium complexes.
نویسندگان
چکیده
Attempts to generate a proposed rhodium hydride catalytic intermediate instead resulted in isolation of (Cp*H)Rh(bpy)Cl (1), a pentamethylcyclopentadiene complex, formed by C-H bond-forming reductive elimination from the fleeting rhodium hydride. The hydride transfer ability of diene 1 was explored through thermochemistry and hydride transfer reactions, including the reduction of NAD(+).
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 58 شماره
صفحات -
تاریخ انتشار 2016